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205. From a TV show; based on comics; presumed Larry Parr; Fantastic Four by Stan Lee, Jack Kirby; 80s
218. From a TV show; based on comics; presumed Donald F. Glut; X-Men by Gary Friedrich, George Tuska, John Verpoorten; 80s
223. Original TV character; presumed Mairghread Scott; 10s
Main characters
Spider-Man 2
Secret Warriors1
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223 Kevin, Marvel Rising
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Kevin is correct. List updated. With things so close to the end I'll give a big clue: each of the two remaining characters is seen in a different character's origin.
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218 Mr Drake (possibly William, but Iceman's father regardless of first name), Spider-Man and His Amazing FriendsĀ
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205 Victor von Doom's college associate who tried to warn him his figures were off (not named as Reed Richards, but presumably), Spider-Man 1981
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Those are correct. For convenience sake we can call the latter character Reed. I'll start the next round shortly. Drake had the bonus shots.
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And really it's not that much of a stretch to assume that last guy is Reed.