All other identifications are correct.

Loki wrote:

zuckyd1 wrote:

39 Nathan (Next Men)

Right title, wrong character, though you've pictured the right person.

Jack

87 Cannibal {{Godzilla, such language!}} aka "CF" (Prison Pit)

82 & 83 Boston and Emily Zegas

62 David Mazzucchelli's Asterios Polyp

69 Newman Xeno (Casanova)

114 Gwen (12 Reasons Why I love Her)

89 Tristan (Love the Way You Love)

The remaining clues again, now we are down to five (and probably only three identifications left): 
36 Can't help with this one - no one seems to have been able to identify him.

37 Kirbyesque myths from the 2000s.

81 No clues, doesn't seem like anyone has managed to identify this one yet.

88 Originally semi-autobiographical webcomic, later published in print by Image in the late 2000s.

111 Spanish SF hero dating back to the 1980s. Published in English by Catalan in the 80s and Dark Horse in the 90s. 

88 Emi Lenox (Emitown)

zuckyd1 wrote:

Loki wrote:

37 Kirbyesque myths from the 2000s.

I got nothing. Searched through Topps/Dynamite Kirbyverse but didn't see any matches.

Not Kirby himself, but every review makes the comparison to the art and story homaging his style. Self-published so mentioning the publisher would be virtually the same as naming the character. Myth was a deliberate word choice on my part.

zuckyd1 wrote:

37 8-Opus

And that's the last one I think we're likely to get for a bit. The remaining two haven't been identified by anyone else I've found who was trying to figure out all the identities, though 36 does look vaguely familiar.

We've actually managed to identify six characters that, afaik, no one else managed to. It'd be nice to get the last two, but I'll declare this one semi-closed. 
 

zuckyd1 wrote:

Loki wrote:

We've actually managed to identify six characters that, afaik, no one else managed to. It'd be nice to get the last two, but I'll declare this one semi-closed.  

Which 6?

60 Jane Legit (they'd identified Billy Dogma, but not her weirdly)
61 Jack (again, they'd got his co-star, but not him)
64 Jopo de Pojo
74 the zombie head from Walking Dead - albeit this isn't an identification we're 100% sure of
82 Boston Zegas (another case of getting one of the characters [his sister] but not the other)
120 V - though to be fair, this is because they'd overlooked his portrait altogether.
 

zuckyd1 wrote:

What was the Big Numbers connection?

When I was trying to figure out clues, I did some internet research on the more obscure characters that I didn't know much about, and found a site mentioning one of the artists behind a character supposedly got his break doing art for Big Numbers. However, when I was later refining the clues, I couldn't remember which character the clue referred to, so I went to check Big Numbers to remind myself - and of course found out that the only artist was Bill Sienkiewicz. So my clue was wrong, hence why I didn't use it in the final round of clues. Either I misread what that site I had found was saying, or it was giving bad info. Not sure which.