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44 Normal, Dark Angel
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64 Jacques, Super (movie)
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60 Jason "future US President" Wynn, Spawn
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98 Rickshaw, All Superheroes Must Die
This one wasn't easy - James Remar's been in a ridiculous number of superhero movies and shows.
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101 Grigori Rasputin, del Toro Hellboy
Here seen with the Infinity Gauntlet.
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51 Frenchie, The Boys
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40 Nathan Clay, Alphas
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24 Diana Palmer, The Phantom movie
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14 Donald Lydecker, Dark Angel
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13 Lisa Madigan, Robocop The Series
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23 Casey "You have failed this city" Jones, 2014 TMNT movie
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15 Tina Walsh, WolfCop
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Those are correct; list updated. I do try to avoid toy images, but they're bound to slip in sometimes. For 157, although she's called The Female in the comics, the show calls her Kimiko Miyashiro, but I knew you had the right character. I suspect for the next few collages, you'll soon be nostalgic for when challenges like figuring out which character James Remar is playing was considered difficult.
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7 Sorceror, 52 Miss Dazzle, Electra Woman and DynaGirl (1970s version)
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154 Spider Lady, Electra Woman and DynaGirl (1970s version)
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37 Princess Cleopatra, Electra Woman and DynaGirl (1970s)
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22 Pharaoh, Electra Woman and DynaGirl (1970s)
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141 Frank Heflin, Electra Woman and DynaGirl (1970s)
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54 The Phantom (Snr), Phantom movie
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38 Xander Drax, Phantom movie
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49 Sarah Helgeland, Super
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129 Roxanne Caldwell, Automan
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20 Leora Maxwell, MANTIS
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5 Taylor Savage, MANTIS
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145 Captain Boyd, Automan
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138 John Stonebrake, MANTIS
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99 Rachel Adams, Street Hawk
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68 Sala, Phantom movie
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143 Ace the Wonder Dog, Phantom serial
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112 Diana Palmer, Phantom serial